Mechanisms of photoinduced fluidity in chalcogenide glasses: Molecular orbital analyses

Photoinduced Fluidity and Viscoelasticity in Chalcogenide Glasses

This work is an attempt to apply conventional mechanical testing to characterize the photoinduced viscoelastic behavior of chalcogenide glasses. Creep or relaxation-recovery experiments are usually performed to characterize the delayed elastic contribution to deformation, during thermally activated flow. In this paper, relaxation-recovery is used to characterize delayed elasticity under irradia...

Molecular Struct’ure and Crystallization Behavior of Chalcogenide Glasses

Isothermal crystallization of ternary (Ge,S,), -X(Sn,S,), glasses is examined over the glass forming range 0 < x < 0.6. Time-temperature-transformation (TIT) curves are obtained using scanning calorimetry. The results show that both nucleation and growth processes dominate crystallization of the glasses in the range 0 < .Y < 0.25, but only growth processes are found to occur once x 2 0.25. The ...

Crystallization Kinetics of Chalcogenide Glasses

Chalcogenide glasses are disordered non crystalline materials which have pronounced tendency their atoms to link together to form link chain. Chalcogenide glasses can be obtained by mixing the chalcogen elements, viz, S, Se and Te with elements of the periodic table such as Ga, In, Si, Ge, Sn, As, Sb and Bi, Ag, Cd, Zn etc. In these glasses, short-range inter-atomic forces are predominantly cov...

Photodarkening profiles and kinetics in chalcogenide glasses.

Numerical studies of the vibrational isocoordinate rule in chalcogenide glasses

Many properties of alloyed chalcogenide glasses can be closely correlated with the average coordination of these compounds. This is the case, for example, of the ultrasonic constants, dilatometric softening temperature and the vibrational densities of states. What is striking, however, is that, at a given average coordination, these properties are nevertheless almost independent of the elementa...